Didn't you get a free e-tron charging service subscription with your car? Ionity is 33 pence per kWh with it. Same price if you use the Elli app and pay the monthly sub which is effectively the replacement for the etron charging service.
Think everything has been covered with the charging speeds, it's nothing unique to Audi, Teslas have an even narrower band where they can get max speed. If you plug in at say 5% in the GT with the battery at an ideal temperature you should be able to sustain over 250kW up to around 40%. Even with a properly pre-conditioned battery if I start a charge around 40% I'll only get around 150kW though. The benefit it though that the car will maintain a higher charge rate for longer as the % climbs as the battery wasn't cooked earlier on - you should be able to keep over 50kW to over 95%.
In summary, if you want max rates, as low a SoC as possible, and always use the Audi navigation to the HPC charger and remember the battery will take some time to warm up after a prolonged stop even with pre-conditioning, so charging after a long drive is much better when things are nice and warm than charging first thing in the day.
As an aside, if you end up joining the club of owners with broken heaters, you'll only get around 50kW as the car can't condition the battery.